Springer Netherlands
Dordrecht
11243
0340-4285
1572-901X
Transition Metal Chemistry
Transition Met Chem
Chemistry
Inorganic Chemistry
Physical Chemistry
Catalysis
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2010
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2010
Springer Science+Business Media B.V.
2010
9399
10.1007/s11243-010-9399-1
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Cobalt(II) silanethiolato complexes with dimethylpyridines: crystal structures and spectroscopic studies
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2010
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The Author(s)
2010
Agnieszka
Pladzyk
+48-58-3472329
+48-58-3472694
apladzyk@chem.pg.gda.pl
Joanna
Olszewska
Katarzyna
Baranowska
Anna
Maria
Dziurzyńska
Department of Inorganic Chemistry
University of Technology
G. Narutowicz St. 11/12
80-233
Gdańsk
Poland
Abstract
Cobalt(II) tri-tert-butoxysilanethiolates with 2,5-dimethylpyridine, 3,4-dimethylpyridine and 3,5- dimethylpyridine co-ligands have been synthesized by reaction of bimetallic [Co{μ-SSi(O
t
Bu)3}{SSi(O
t
Bu)3}(NH3)]2 with the appropriate pyridines. The complexes were characterized by elemental analysis, single-crystal X-ray structure determination, IR and UV–Vis spectroscopy. These complexes are tetra- or penta-coordinated with CoN2S2 and CoNO2S2 cores, respectively.
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